A nonsymmetric Dy<sub>2</sub> single-molecule magnet with two relaxation processes triggered by an external magnetic field: a theoretical and integrated EPR study of the role of magnetic-site dilution-Reference-Cited by-同舟云学术

A nonsymmetric Dy₂ single-molecule magnet with two relaxation processes triggered by an external magnetic field: a theoretical and integrated EPR study of the role of magnetic-site dilution

Published:2022 Issue:5 Volume:51 Page:1985-1994
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Lalioti Nikolia¹,Nastopoulos Vassilis¹,Panagiotou Nikos²,Tasiopoulos Anastasios²^ORCID,Ioannidis Nikolaos³^ORCID,van Slageren Joris⁴^ORCID,Zhang Peng⁴⁵,Rajaraman Gopalan⁶^ORCID,Swain Abinash⁶,Tangoulis Vassilis¹^ORCID

Affiliation:

1. Department of Chemistry, Laboratory of Inorganic Chemistry, University of Patras, 26504 Patras, Greece

2. Department of Chemistry, University of Cyprus, 1678 Nicosia, Cyprus

3. Institute of Nanoscience and Nanotechnology, NCSR “Demokritos”, 153 10 Aghia Paraskevi Attikis, Greece

4. School of Chemistry& Chemical Engineering, Shaanxi Normal University Xi'an, 710199, China

5. Institut für Physikalische Chemie, Universität Stuttgart, Pfaffenwaldring 55, D-70569 Stuttgart, Germany

6. Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai - 400 076, India

Abstract

A non-symmetric Dy2 single molecule magnet revealing two magnetization relaxation processes under a 1500 G external magnetic field and a ferromagnetic interaction between the DyIII ions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT04089H

Reference49 articles.

1. Lanthanide Single-Molecule Magnets

2. A Journey in Lanthanide Coordination Chemistry: From Evaporable Dimers to Magnetic Materials and Luminescent Devices

3. Assessing the exchange coupling in binuclear lanthanide(iii) complexes and the slow relaxation of the magnetization in the antiferromagnetically coupled Dy2 derivative

4. Exchange‐Biasing in a Dinuclear Dysprosium(III) Single‐Molecule Magnet with a Large Energy Barrier for Magnetisation Reversal

5. Single-Molecule Magnet Behavior for an Antiferromagnetically Superexchange-Coupled Dinuclear Dysprosium(III) Complex

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