An efficient catalytic method for hydrophosphination of heterocumulenes with diethylzinc as precatalyst without a solvent-Reference-Cited by-同舟云学术

An efficient catalytic method for hydrophosphination of heterocumulenes with diethylzinc as precatalyst without a solvent

Published:2021 Issue:43 Volume:50 Page:15488-15492
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhang Bingyi¹,Ma Xiaoli¹^ORCID,Yan Ben¹,Ni Congjian¹,Yu Hailong¹,Yang Zhi¹,Roesky Herbert W.²^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, P. R. China

2. Institute of Inorganic Chemistry, Georg-August-Universität Göttingen, Göttingen Tammannstrasse 4, D-37077, Germany

Abstract

The hydrophosphination of heterocumulenes with Ph2PH using diethylzinc as precatalyst in neat conditions, which shows excellent catalytic effects. Intermediate is characterized to corroborate the proposed catalytic mechanism.

Funder

National Natural Science Foundation of China

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02706A

Reference49 articles.

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5. Notiz über eine neue Reihe organischer Körper, welche Metalle, Phosphor u. s. w. enthalten

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