Isothiourea-catalyzed formal enantioselective conjugate addition of benzophenone imines to β-fluorinated α,β-unsaturated esters-Reference-Cited by-同舟云学术

Isothiourea-catalyzed formal enantioselective conjugate addition of benzophenone imines to β-fluorinated α,β-unsaturated esters

Published:2022 Issue:49 Volume:58 Page:6886-6889
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Lapetaje Jerson E.¹,Young Claire M.¹^ORCID,Shu Chang¹,Smith Andrew D.¹^ORCID

Affiliation:

1. EaStCHEM, School of Chemistry, University of St Andrews, North Haugh, St. Andrews KY16 9ST, UK

Abstract

The isothiourea-catalyzed enantioselective conjugate addition of 2-hydroxybenzophenone imine derivatives to α,β-unsaturated esters gives β-imino esters with up to 97 : 3 er.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC01936A

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5. Asymmetric synthesis of R-β-amino butanoic acid and S-β-tyrosine: Homochiral lithium amide equivalents for Michael additions to α,β-unsaturated esters.

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