A mesoporous Zr-based metal–organic framework driven by the assembly of an octatopic linker-Reference-Cited by-同舟云学术

A mesoporous Zr-based metal–organic framework driven by the assembly of an octatopic linker

Published:2023 Issue:50 Volume:59 Page:7803-7806
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ortín-Rubio Borja¹²^ORCID,Perona-Bermejo Cristina³,Suárez del Pino José A.¹²,Carmona Francisco J.³^ORCID,Gándara Felipe⁴^ORCID,Navarro Jorge A. R.³^ORCID,Juanhuix Judith⁵^ORCID,Imaz Inhar¹²,Maspoch Daniel¹²⁶^ORCID

Affiliation:

1. Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, Barcelona 08193, Spain

2. Departament de Química, Facultat de Ciències, Universitat Autònoma de Barcelona, Bellaterra 08193, Spain

3. Departamento de Química Inorgánica, Universidad de Granada, Av. Fuentenueva S/N, Granada 18071, Spain

4. Materials Science Institute of Madrid (ICMM), Consejo Superior de Investigaciones Científicas (CSIC), Calle Sor Juana Inés de la Cruz, 3, Madrid 28049, Spain

5. ALBA Synchrotron, Cerdanyola del Vallès, Barcelona 08290, Spain

6. ICREA, Pg. Lluís Companys 23, Barcelona 08010, Spain

Abstract

We present BCN-348, a new high-connected MOF built from an 8-c cubic Zr-oxocluster and an 8-c organic linker. BCN-348 shows a 3,4,8-c eps net, mesoporosity, hydrolytic stability, and acts as a catalyst for hydrolysis of a nerve-agent simulant.

Funder

H2020 European Research Council

Agencia Estatal de Investigación

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC01831H

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