Synthesis, structure, and reactions of a copper–sulfido cluster comprised of the parent Cu2S unit: {(NHC)Cu}2(μ-S)-Reference-Cited by-同舟云学术

Synthesis, structure, and reactions of a copper–sulfido cluster comprised of the parent Cu2S unit: {(NHC)Cu}2(μ-S)

Published:2016 Issue:1 Volume:7 Page:589-595
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhai Junjie¹²³⁴,Filatov Alexander S.¹²³⁴,Hillhouse Gregory L.¹²³⁴,Hopkins Michael D.¹²³⁴

Affiliation:

1. Department of Chemistry

2. The University of Chicago

3. Chicago

4. USA

Abstract

The first CuI2(μ-S) complex, {(IPr*)Cu}₂(μ-S) (IPr* = 1,3-bis(2,6-(diphenylmethyl)-4-methylphenyl)imidazol-2-ylidene), has been synthesized, and its structure has been characterized crystallographically.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC03258J

Reference68 articles.

1. Chalcogen-Bridged Copper Clusters

2. Chalcogenide clusters of copper and silver from silylated chalcogenide sources

3. Synthesis and Structure of a CuI3S Cluster Unsupported by Other Bridging Ligands

4. Assembly, Structure, and Reactivity of Cu4S and Cu3S Models for the Nitrous Oxide Reductase Active Site, CuZ*

5. Synthesis and luminescent properties of a novel tetranuclear copper(I) cluster containing a µ4-sulfur moiety. X-Ray crystal structure of [Cu4(µ-dppm)4(µ4-S)](PF6)2·2Me2CO [dppm = bis(diphenylphosphino)methane]

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