An iron-catalyzed nitrene transfer reaction of nitrosobenzenes with N-acyloxyamides for accessing N-acyl azoxy molecules

Author:

Huang Weimin1,Yan Haobo1,Wang Qianqian1,Chen Jianhui1ORCID,Luo Yanshu1,Xia Yuanzhi1ORCID

Affiliation:

1. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China

Abstract

A nitrene transfer reaction of nitrosobenzenes with N-acyloxyamides using FeCl2·4H2O as a cheap and commercially available catalyst was developed for facile synthesis of N-acyl azoxy compounds with high functional-group compatibility.

Funder

Wenzhou University

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

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5. A new family of lanthanide-based coordination polymers with azoxybenzene-3,3′,5,5′-tetracarboxylic acid as ligand

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