Fe-catalyzed B–H and Si–H insertion reactions of <i>gem</i>-dihaloalkanes-Reference-Cited by-同舟云学术

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Fe-catalyzed B–H and Si–H insertion reactions of gem-dihaloalkanes

Published:2024 Issue:8 Volume:11 Page:2241-2248
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Wang Xinyu¹²³,Wang Zhaobin²³^ORCID

Affiliation:

1. Department of Chemistry, Zhejiang University, Hangzhou 310058, China

2. Key Laboratory of Precise Synthesis of Functional Molecules of Zhejiang Province, Department of Chemistry, School of Science, Westlake University, Hangzhou 310030, China

3. Institute of Natural Sciences, Westlake Institute for Advanced Study, Hangzhou 310024, China

Abstract

We present an approach involving Fe-catalyzed B–H and Si–H insertion of gem-dichloroalkanes. In contrast to previous strategies, our method uses gem-dihaloalkanes as non-stabilized carbene precursors and operates through a radical reaction pathway.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO00136B

Reference93 articles.

1. Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds

2. Electron-Precise Coordination Modes of Boron-Centered Ligands

3. Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners

4. Stereospecific Couplings of Secondary and Tertiary Boronic Esters

5. Synthesis and Applications of Boronic Acid-Containing Polymers: From Materials to Medicine

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