Enantio- and regioselective asymmetric allylic substitution using a chiral aminophosphinite ruthenium complex: an experimental and theoretical investigation-Reference-Cited by-同舟云学术

Enantio- and regioselective asymmetric allylic substitution using a chiral aminophosphinite ruthenium complex: an experimental and theoretical investigation

Published:2021 Issue:62 Volume:11 Page:39319-39327
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Jena Rajesh K.¹^ORCID,Das Dhiraj²³^ORCID

Affiliation:

1. Centre of Excellence in Advanced Materials and Applications, Utkal University, Vani Vihar, Bhubaneswar-751004, India

2. Department of Chemistry, Indian Institute of Technology Kharagpur, Kharagpur 721302, India

3. Department of Chemistry, University of Calcutta, Kolkata, India

Abstract

A new chiral –P,N-ligand, and its ruthenium(ii) complex has been synthesized, which catalyzed the highly regioselective O-allylation of phenols and carboxylic acids to afford the branched product as the major product with high to low enantioselectivities.

Funder

Rashtriya Uchchatar Shiksha Abhiyan

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RA/D1RA06824E

Reference53 articles.

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4. (η6-Arene)ruthenium(II) complexes containing enantiomerically pure (β-aminoalkyl)phosphines or a (β-aminoalkyl) phosphinite: synthesis, stereochemical and kinetic studies

5. Amino‐phosphanes in Rh I ‐Catalyzed Hydroformylation: Hemilabile Behavior of P,N Ligands under High CO Pressure and Catalytic Properties

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