Radical homopolymerization of vinyl ethers activated by Li<sup>+</sup>-π complexation in the presence of CH<sub>3</sub>OLi and LiI-Reference-Cited by-同舟云学术

Radical homopolymerization of vinyl ethers activated by Li⁺-π complexation in the presence of CH₃OLi and LiI

Published:2022 Issue:8 Volume:13 Page:1098-1106
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Duan Junjin¹,Gong Yi¹,Chen Dong¹,Ma Yuhong¹^ORCID,Song Changtong¹,Yang Wantai¹

Affiliation:

1. Beijing Engineering Research Center of Syntheses and Applications of Waterborne Polymers College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Abstract

The radical polymerization activity of both hydroxyl and alkyl vinyl ether monomers is significantly activated by Li+-π complexation with CH3OLi or LiI.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2022/PY/D1PY01619A

Reference49 articles.

1. ESR studies on radical polymerization of vinyl ethers

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3. Specific Polymerization Mechanism Involving β-Scission of Mid-Chain Radical Yielding Oligomers in the Free-Radical Polymerization of Vinyl Ethers

4. Direct Radical Polymerization of Vinyl Ethers: Reversible Addition–Fragmentation Chain Transfer Polymerization of Hydroxy-Functional Vinyl Ethers

5. Design of Hydroxy-Functionalized Thermoresponsive Copolymers: Improved Direct Radical Polymerization of Hydroxy-Functional Vinyl Ethers

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