Ultrafast charge transfer of stiboviologens for electrochromism and visible light-induced α-amino C(sp3)–H functionalization

Author:

Xu Liang1,Zhang Lei2,Qiao Yi1,Zheng Haifeng1,Li Guoping1,Rao Bin3ORCID,Zhang Mingming4ORCID,Ma Wenqiang15,He Gang1ORCID

Affiliation:

1. Frontier Institute of Science and Technology, State Key Laboratory for Strength and Vibration of Mechanical Structures, Xi'an Key Laboratory of Electronic Devices and Material Chemistry, Engineering Research Center of Key Materials for Efficient Utilization of Clean Energy of Shaanxi Province, Future Industrial Innovation Institute of Emerging Information Storage and Smart Sensor, Xi'an Jiaotong University, Xi'an, Shaanxi Province, 710054, China

2. School of Optoelectronic Engineering, Xidian University, Xi'an, Shaanxi, 710126, China

3. School of Chemistry, Xi'an Jiaotong University, Xi'an, Shaanxi Province, 710054, China

4. School of Materials Science and Engineering Xi'an Jiaotong University, Xi'an, Shaanxi, 710049, China

5. Department of Radiation Oncology, The First Affiliated Hospital of Xi'an Jiaotong University, Xi'an, 710061, China

Abstract

Four stiboviologens (SbV2+) with tunable optoelectronic properties were synthesized. Stiboviologens exhibited ultrafast MLCT (metal-to-ligand charge transfer) processes and had great visible light catalytic performance.

Funder

Fundamental Research Funds for the Central Universities

National Key Research and Development Program of China

National Natural Science Foundation of China

Natural Science Foundation of Shaanxi Province

China Postdoctoral Science Foundation

Xi’an Jiaotong University

Shaanxi Science and Technology Association

National Postdoctoral Program for Innovative Talents

Publisher

Royal Society of Chemistry (RSC)

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