Chromophore-radical excited state antiferromagnetic exchange controls the sign of photoinduced ground state spin polarization-Reference-Cited by-同舟云学术

Chromophore-radical excited state antiferromagnetic exchange controls the sign of photoinduced ground state spin polarization

Published:2021 Issue:41 Volume:12 Page:13704-13710
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kirk Martin L.¹^ORCID,Shultz David A.²,Hewitt Patrick²,Stasiw Daniel E.²,Chen Ju¹,van der Est Art³

Affiliation:

1. Department of Chemistry and Chemical Biology, The University of New Mexico, MSC03 2060, 1 University of New Mexico, Albuquerque, NM 87131-0001, USA

2. Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, USA

3. Department of Chemistry, Brock University, St. Catharines, Ontario, Canada L2S 3A1

Abstract

A change in the sign of the ground state electron spin polarization (ESP) is reported in complexes where an organic radical (nitronylnitroxide, NN) is covalently attached to a donor–acceptor chromophore via two different meta-phenylene bridges.

Funder

Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC02965G

Reference45 articles.

1. Exploiting chemistry and molecular systems for quantum information science

2. Quantum computing with molecular spin systems