Ag2O-catalysed nucleophilic isocyanation: selective formation of less-stable benzylic isonitriles
Author:
Affiliation:
1. Division of Applied Chemistry and Frontier Chemistry Centre
2. Faculty of Engineering
3. Hokkaido University
4. Sapporo
5. Japan
6. Graduate School of Chemical Sciences and Engineering
Abstract
Both primary and secondary benzylic isonitriles were exclusively produced by the Ag2O-catalysed reaction of benzylic phosphates and trimethylsilyl cyanide without formation of the thermodynamically favoured regioisomers, benzylic nitriles.
Funder
Japan Society for the Promotion of Science
Sumitomo Foundation
Hokkaido University
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/QO/D0QO00336K
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4. Isocyanide Chemistry , ed. V. G. Nenadjenko , Wiley-VCH , Weinheim , 2012
5. THE USE OF ISOCYANIDES IN HETEROCYCLIC SYNTHESIS. A REVIEW
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