Tuning the stacking behaviour of a 2D covalent organic framework through non-covalent interactions
Author:
Affiliation:
1. Max Planck Institute for Solid State Research
2. 70569 Stuttgart
3. Germany
4. Ludwig Maximilians University of Munich
5. 81377 Munich
6. Institut de Physique
7. École Polytechnique Fédérale de Lausanne
Abstract
The distinct stacking behaviour of two related 2D covalent organic frameworks is traced back to geometric and electronic features of their building blocks. Self-complementarity and donor–acceptor-type interactions are identified as design principles to access highly crystalline COFs.
Funder
Bundesministerium für Bildung und Forschung
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Materials Science
Link
http://pubs.rsc.org/en/content/articlepdf/2017/QM/C6QM00378H
Reference40 articles.
1. Covalent Chemistry beyond Molecules
2. Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials
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5. Reticular Synthesis of Microporous and Mesoporous 2D Covalent Organic Frameworks
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