A hybrid silylene-Pd catalyst: efficient C–N cross-coupling of sterically bulky amines and chiral amines-Reference-Cited by-同舟云学术

A hybrid silylene-Pd catalyst: efficient C–N cross-coupling of sterically bulky amines and chiral amines

Published:2024 Issue:73 Volume:60 Page:9958-9961
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kaulage Sandeep H.¹^ORCID,Parvin Nasrina¹,Khopade Kishor V.²³,Khan Shabana¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Science Education and Research Pune, Dr Homi Bhabha Road, Pashan, Pune-411008, India

2. Polymer Science and Engineering Division, CSIR-National Chemical Laboratory, Pune, Dr Homi Bhabha Road, Pashan, Pune-411008, India

3. Academy of Scientific and Innovative Research (AcSIR), Sector 19, Kamla Nehru Nagar, Ghaziabad 201002, Uttar Pradesh, India

Abstract

Herein, we report a hybrid silylene-based bidentate ligand (SiNP)–Pd(0) catalytic system, which performs the C–N coupling of difficult substrates, e.g., sterically bulky amines and chiral amines.

Funder

Science and Engineering Research Board

Indian Institute of Science Education and Research Pune

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC03108C

Reference38 articles.

1. Synthesis and Unexpected Coordination of a Silicon(II)-Based SiCSi Pincerlike Arene to Palladium

2. Cobalt-Catalyzed C(sp2)-H Borylation: Mechanistic Insights Inspire Catalyst Design

3. Preparation, structure and catalytic properties of a binuclear Pd(0) complex with bridging silylene ligands

4. Chemistry of functionalized silylenes

5. Pushing the σ-Donor Strength in Iridium Pincer Complexes: Bis(silylene) and Bis(germylene) Ligands Are Stronger Donors than Bis(phosphorus(III)) Ligands