Discrete unusual mixed-bridged trinuclear CoIII2CoII and pentanuclear NiII coordination complexes supported by a phenolate-based ligand: theoretical and experimental magneto-structural study

Author:

Richa 1234,Rathnam Muni5674,Kumar Akhilesh891048,Verma Indresh89104,Kłak Julia11121314ORCID,Cano Joan15161718ORCID,Mota Antonio J.1920212218ORCID,Rajput Amit1234,Arora Himanshu1234ORCID

Affiliation:

1. School of Engineering and Sciences

2. G.D. Goenka University

3. Gurugram

4. India

5. Department of Chemical Sciences

6. Indian Institute of Science Education and Research Kolkata

7. Mohanpur 741 246

8. Department of Chemistry

9. Indian Institute of Technology Kanpur

10. Kanpur 208016

11. Faculty of Chemistry

12. University of Wroclaw

13. Wroclaw 50-383

14. Poland

15. Department of Química Inorgànica/Instituto de Ciencia Molecular (ICMol)

16. Facultat de Quimica de la Universitat de València, C/Catedrático Jose Beltrán 2

17. 46980 Paterna

18. Spain

19. Department of Inorganic Chemistry

20. Faculty of Science

21. University of Granada

22. Granada

Abstract

We report a combined computational and experimental magnetostructural correlation in trinuclear mixed valence cobalt and pentanuclear nickel complexes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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