Synthesis of hydrocarbon-soluble, methyl-substituted highly branched polysilanes via the Wurtz-type reductive coupling of trifunctional trisilanes and their pyrolysis to silicon carbide-Reference-Cited by-同舟云学术

Synthesis of hydrocarbon-soluble, methyl-substituted highly branched polysilanes via the Wurtz-type reductive coupling of trifunctional trisilanes and their pyrolysis to silicon carbide

Published:2015 Issue:106 Volume:5 Page:87445-87455
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Deller K.¹²³⁴⁵,Rieger B.¹²³⁴⁵

Affiliation:

1. Wacker-Lehrstuhl für Makromolekulare Chemie

2. Institut für Siliciumchemie

3. Technische Universität München

4. 85748 Garching

5. Germany

Abstract

(ClMe₂Si)₂SiMeCl was successfully converted into a hydrocarbon-soluble, highly branched polymethylsilane, which is usable as soluble precursor for the pyrolytic preparation of SiC.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA19266H

Reference81 articles.

1. M. A. Brook , Silicon in Organic, Organometallic and Polymer Chemistry, Wiley, New York, 2000

2. The polysilane high polymers

3. Polysilane high polymers

4. R. West , in The Chemistry of Organic Silicone Compounds, ed. S. Patai and Z. Rappoport, Wiley, Chichester, UK, 1989, vol. 2, pp. 1207–1240

5. Synthesis and Characterization of Polysilanes

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