Do primary carriers of both positive charge and unpaired electron spin exist in irradiated propylene carbonate?
Author:
Affiliation:
1. Voevodsky Institute of Chemical Kinetics and Combustion
2. Siberian Branch of the Russian Academy of Science
3. Novosibirsk 630090
4. Russia
5. Novosibirsk State University
Abstract
Magnetic field sensitive fluorescence from irradiated propylene carbonate solutions indicates the existence of previously unobserved radical cations formed from the solvent molecules.
Funder
Russian Foundation for Basic Research
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CP/C6CP07477D
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1. Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
2. Electrolytes and Interphases in Li-Ion Batteries and Beyond
3. Role of PF6− in the radiolytical and electrochemical degradation of propylene carbonate solutions
4. Theoretical Insight into Oxidative Decomposition of Propylene Carbonate in the Lithium Ion Battery
5. Efficient approach to include molecular polarizations using charge and atom dipole response kernels to calculate free energy gradients in the QM/MM scheme
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