The Achilles' heel of iron-based catalysts during oxygen reduction in an acidic medium

Author:

Choi Chang Hyuck1234ORCID,Lim Hyung-Kyu56784ORCID,Chung Min Wook1234,Chon Gajeon1234,Ranjbar Sahraie Nastaran910111213,Altin Abdulrahman14151617,Sougrati Moulay-Tahar910111213ORCID,Stievano Lorenzo910111213ORCID,Oh Hyun Seok1819204,Park Eun Soo1819204ORCID,Luo Fang521222317,Strasser Peter521222317ORCID,Dražić Goran24252627ORCID,Mayrhofer Karl J. J.1415161728ORCID,Kim Hyungjun56784ORCID,Jaouen Frédéric910111213ORCID

Affiliation:

1. School of Materials Science and Engineering

2. Gwangju Institute of Science and Technology

3. 61005 Gwangju

4. Republic of Korea

5. Department of Chemistry

6. Graduate School of EEWS

7. Korea Advanced Institute of Science and Technology

8. 34141 Daejeon

9. Institut Charles Gerhardt Montpellier

10. UMR CNRS 5253

11. Agrégats

12. Interfaces et Matériaux pour l'Energie

13. Université de Montpellier

14. Department of Interface Chemistry and Surface Engineering

15. Max-Planck Institut für Eisenforschung GmbH

16. 40237 Düsseldorf

17. Germany

18. Department of Materials Science and Engineering

19. Seoul National University

20. 08826 Seoul

21. Chemical Engineering Division

22. Technical University Berlin

23. 10623 Berlin

24. Department of Materials Chemistry

25. National Institute of Chemistry

26. 1001 Ljubljana

27. Slovenia

28. Helmholtz-Institute Erlangen-Nürnberg for Renewable Energy (IEK-11)

Abstract

Exposing Fe–N–C catalysts to H2O2-byproduct leaves their catalytic sites untouched but decreases the turnover frequency via oxidation of the carbon surface.

Funder

Agence Nationale de la Recherche

H2020 Industrial Leadership

National Research Foundation of Korea

Horizon 2020 Framework Programme

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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