Supramolecular “baking powder”: a hexameric halogen-bonded phosphonium salt cage encapsulates and functionalises small-molecule carbonyl compounds-Reference-Cited by-同舟云学术

Supramolecular “baking powder”: a hexameric halogen-bonded phosphonium salt cage encapsulates and functionalises small-molecule carbonyl compounds

Published:2024 Issue:1 Volume:15 Page:298-306
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Marrett Joseph M.¹²^ORCID,Titi Hatem M.²^ORCID,Teoh Yong²,Friščić Tomislav¹²^ORCID

Affiliation:

1. School of Chemistry, University of Birmingham, Edgbaston, Birmingham, B15 2TT, UK

2. Department of Chemistry, McGill University, 801 Sherbrooke St. W. Montreal, H3A 0B8, Canada

Abstract

We report halogen-bonded supramolecular cages based on a Wittig-type phosphonium salt, which pre-formulate aldehydes and ketones for a mechanochemical Wittig olefination and enable the conversion of an aldehyde to an enediyne.

Funder

Leverhulme Trust

Government of Canada

Natural Sciences and Engineering Research Council of Canada

University of Birmingham

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D2SC04615F

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