Ligand and solvent control of selectivity in the C–H activation of a pyridylimine-substituted 1-naphthalene; a combined synthetic and computational study-Reference-Cited by-同舟云学术

Ligand and solvent control of selectivity in the C–H activation of a pyridylimine-substituted 1-naphthalene; a combined synthetic and computational study

Published:2018 Issue:33 Volume:47 Page:11680-11690
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Simayi Rena¹²³⁴,Gillbard Simone M.⁵⁶⁷⁴,Cross Warren B.⁵⁶⁷⁴^ORCID,Hope Eric G.¹²³⁴,Singh Kuldip¹²³⁴,Solan Gregory A.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Leicester

3. Leicester LE1 7RH

4. UK

5. School of Science and Technology

6. Nottingham Trent University

7. Nottingham NG11 8NS

Abstract

The site-selectivity of C–H activation in a 1-substituted naphthalene is explored using palladium(ii) chloride salts; the experimental findings are fully supported by DFT calculations.

Funder

University of Leicester

Nottingham Trent University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT02565G

Reference66 articles.

1. Designing Catalysts for Functionalization of Unactivated C–H Bonds Based on the CH Activation Reaction

2. Recent Advances in the Platinum-mediated CH Bond Functionalization

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4. The Essential Role of Bond Energetics in C–H Activation/Functionalization

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