A free-radical-promoted stereospecific denitro silylation of β-nitroalkenes with silanes-Reference-Cited by-同舟云学术

A free-radical-promoted stereospecific denitro silylation of β-nitroalkenes with silanes

Published:2019 Issue:19 Volume:6 Page:3365-3368
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zhang Xi¹²³⁴,Liu Ming-Xia¹²³⁴,Wang Tong-Lin¹²³⁴,Wang Yong-Qing¹²³⁴,Wang Xi-Cun¹²³⁴^ORCID,Quan Zheng-Jun¹²³⁴^ORCID

Affiliation:

1. Gansu International Scientific and Technological Cooperation Base of Water-Retention Chemical Functional Materials; College of Chemistry and Chemical Engineering

2. Northwest Normal University

3. Lanzhou

4. People's Republic of China

Abstract

A novel Cu-promoted approach for the stereospecific synthesis of (E)-vinylsilanes through the denitro C–Si coupling reaction of β-nitroalkenes with silanes.

Funder

National Natural Science Foundation of China

Northwest Normal University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QO/C9QO00819E

Reference40 articles.

1. The oxidation of the carbon-silicon bond

2. Palladium-Catalyzed Intramolecular Coupling of 2-[(2-Pyrrolyl)silyl]aryl Triflates through 1,2-Silicon Migration