Magnetic anisotropy and slow relaxation of magnetisation in double salts containing four- and six-coordinate cobalt(ii) complex ions

Author:

Juráková Jana12ORCID,Santana Vinicius Tadeu1ORCID,Pavlik Ján2ORCID,Moncoľ Ján2ORCID,Nemec Ivan13,Clemente-León Miguel4ORCID,Kuppusamy Senthil Kumar5ORCID,Ruben Mario5,Čižmár Erik6ORCID,Šalitroš Ivan12ORCID

Affiliation:

1. Central European Institute of Technology, Brno University of Technology, Purkyňova 123, 61200 Brno, Czech Republic

2. Department of Inorganic Chemistry, Faculty of Chemical and Food Technology, Slovak University of Technology in Bratislava, Bratislava SK-81237, Slovakia

3. Department of Inorganic Chemistry, Faculty of Science, Palacký University, 17. listopadu 12, 771 46 Olomouc, Czech Republic

4. Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, Catedrático José Beltrán 2, 46980 Paterna, Spain

5. Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

6. Institute of Physics, Faculty of Science, P.J. Šafárik University, Park Angelinum 9, 04154 Košice, Slovakia

Abstract

Four Co(ii) compounds [Co(Ln)2][Co(NCY)4] were prepared, structurally, spectrally and magnetically characterized. The magnetic anisotropy was studied in detail and AC susceptibility study revealed field-induced slow relaxation of magnetisation.

Funder

European Regional Development Fund

Univerzita Palackého v Olomouci

Spanish Ministry of Science and Innovation

Generalitat Valenciana

Grantová Agentura České Republiky

Vedecká Grantová Agentúra MŠVVaŠ SR a SAV

Agentúra na Podporu Výskumu a Vývoja

Publisher

Royal Society of Chemistry (RSC)

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