Towards the first theoretical scale of the trans effect in octahedral complexes-Reference-Cited by-同舟云学术

Towards the first theoretical scale of the trans effect in octahedral complexes

Published:2016 Issue:2 Volume:18 Page:982-990
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Guégan Frédéric¹²³⁴⁵,Tognetti Vincent⁶⁷⁸⁹⁴,Joubert Laurent⁶⁷⁸⁹⁴,Chermette Henry¹²³⁴⁵,Luneau Dominique¹¹⁰¹¹⁴⁵,Morell Christophe¹²³⁴⁵

Affiliation:

1. Université de Lyon

2. Institut des Sciences Analytiques

3. UMR 5280

4. CNRS

5. Université Claude Bernard Lyon 1

6. Normandy University

7. COBRA UMR 6014 & FR 3038

8. Université de Rouen

9. INSA Rouen

10. Laboratoire des Multimatériaux et Interfaces

11. UMR 5615

Abstract

In this paper, we show that trans effects in octahedral complexes can primarily be related to differences in the ability, for a given ligand, to cede electron density to the metal cation under the influence of the ligand at the trans position.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C5CP04982B

Reference64 articles.

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2. D. F. Shriver , P. W.Atkins and C. H.Langford, Inorganic Chemistry, Oxford University Press, 2nd edn, 1994

3. Trans influence and mutual influence of ligands coordinated to a central atom

4. The Trans Effect in Complex Inorganic Compounds.

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