Ambient electrocatalytic N2 reduction to NH3 by metal fluorides

Author:

Li Peipei12345,Liu Zaichun678910,Wu Tongwei1234,Zhang Ya1234,Wang Linyu1112134,Wang Li1112134,Ji Lei1234,Zhang Youyu514111516,Luo Yonglan171118194ORCID,Wang Ting123417ORCID,Liu Shanhu201121224ORCID,Wu Yuping678910,Liu Meiling514111516ORCID,Sun Xuping1234ORCID

Affiliation:

1. Institute of Fundamental and Frontier Sciences

2. University of Electronic Science and Technology of China

3. Chengdu 610054

4. China

5. Key Laboratory of Chemical Biology

6. State Key Laboratory of Materials-oriented Chemical Engineering

7. School of Energy Science and Engineering

8. Institute for Advanced Materials

9. Nanjing Tech University

10. Nanjing 211816

11. College of Chemistry and Chemical Engineering

12. Jiangxi Normal University

13. Nanchang 330022

14. Traditional Chinese Medicine Research (Ministry of Education)

15. Hunan Normal University

16. Changsha 410081

17. Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province

18. China West Normal University

19. Nanchong 637002

20. Henan Joint International Research Laboratory of Environmental Pollution Control Materials

21. Henan University

22. Kaifeng 475004

Abstract

LaF3 nanoplates are efficient for electrocatalytic N2 reduction in 0.5 M LiClO4 with a high faradaic efficiency of 16.0% and a large NH3 yield of 55.9 μg h−1 mgcat.−1.

Funder

National Natural Science Foundation of China

Scientific Research Foundation of Hunan Provincial Education Department

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Reference40 articles.

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4. I. Dybkjaer , Ammonia Production Processes , ed. A. Nielsen , Springer , Heidelberg , 1995 , pp. 199–327

5. Light-driven dinitrogen reduction catalyzed by a CdS:nitrogenase MoFe protein biohybrid

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