A thermally stable pH-responsive “supramolecular buckle” based on the encapsulation of 4-(4-aminophenyl)-N-methylpyridinium by cucurbit[8]uril-Reference-Cited by-同舟云学术

A thermally stable pH-responsive “supramolecular buckle” based on the encapsulation of 4-(4-aminophenyl)-N-methylpyridinium by cucurbit[8]uril

Published:2015 Issue:9 Volume:2 Page:1030-1034
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zhou Tian-You¹²³⁴⁵,Qi Qiao-Yan¹²³⁴⁵,Zhang Ying¹²³⁴⁵,Xu Xiao-Na¹²³⁴⁵,Zhao Xin¹²³⁴⁵

Affiliation:

1. Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules

2. Shanghai Institute of Organic Chemistry

3. Chinese Academy of Sciences

4. Shanghai 200032

5. China

Abstract

A CB[8]-based host-guest system forms a thermally stable 1 : 2 complex under neutral conditions and transforms into a 1 : 1 complex upon acidification, which makes it a “supramolecular buckle” to fabricate pH-responsive materials at elevated temperatures.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/QO/C5QO00168D

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