Proton-coupled electron transfer is the dominant mechanism of reduction of haloacetates by the α-hydroxyethyl radical in aqueous media

Author:

Džeba Iva1234ORCID,Bonifačić Marija5234ORCID,Nikšić-Franjić Ivana5234ORCID,Ljubić Ivan5234ORCID

Affiliation:

1. Department of Materials Chemistry

2. Ruđer Bošković Institute

3. HR-10000 Zagreb

4. Croatia

5. Department of Physical Chemistry

Abstract

Reactions of α-hydroxyethyl radical with four haloacetates in non-buffered and buffered aqueous solutions preferably follow the proton-coupled electron transfer pathway.

Funder

Hrvatska Zaklada za Znanost

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference54 articles.

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2. C. von Sonntag , The Chemical Basis of Radiation Biology , Taylor and Francis , London, UK , 1987

3. K.-D. Asmus and M.Bonifačić , in Landolt-Börnstein, Numerical Data and Functional Relationships in Science and Technology , ed. H. Fischer , New Series, Group II, Springer Verlag , Berlin , 1984 , vol. 13b, supplement to vol. II/13b, 1995, vol. 18b

4. Rate Constants for Reactions of Aliphatic Carbon‐Centered Radicals in Aqueous Solution

5. Carbon-Centered Free Radicals and Radical Cations: Structure, Reactivity, and Dynamics (Wiley Series of Reactive Intermediates in Chemistry and Biology) , ed. M. D. Forbes , John Wiley & Sons , Hoboken, NJ , 2010

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