Synthesis of amphiphilic chiral salen complexes and their conformational manipulation at the air–water interface

Author:

Akine Shigehisa12ORCID,Nomura Keisuke2,Takahashi Mizuho2,Sakata Yoko12ORCID,Mori Taizo34,Nakanishi Waka3ORCID,Ariga Katsuhiko34ORCID

Affiliation:

1. Nano Life Science Institute (WPI-NanoLSI), Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan

2. Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan

3. Research Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan

4. Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan

Abstract

New amphiphilic chiral salen complexes having hydrophilic triethyleneglycol chains and a hydrophobic π-extended metallosalen core formed monolayers at the air–water interface, which showed unique conformational changes upon mechanical compression.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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