Probing the coordination environment of Ti3+ ions coordinated to nitrogen-containing Lewis bases-Reference-Cited by-同舟云学术

Probing the coordination environment of Ti3+ ions coordinated to nitrogen-containing Lewis bases

Published:2015 Issue:32 Volume:17 Page:20853-20860
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Morra E.¹²³⁴⁵,Maurelli S.¹²³⁴,Chiesa M.¹²³⁴,Van Doorslaer S.⁵⁶⁷⁸

Affiliation:

1. Dipartimento di Chimica

2. University of Torino Via Giuria

3. 7-10125 Torino

4. Italy

5. University of Antwerp

6. Department of Physics

7. B-2610 Wilrijk

8. Belgium

Abstract

A combined EPR and DFT study on model systems reveals fingerprint ¹⁴N hyperfine and quadrupole data to identify binding of nitrogen-containing Lewis bases to Ti(iii).

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP03417E

Reference42 articles.

1. The different crystalline modifications of TiCl3, a catalyst component for the polymerization of α-olefins. I: α-, β-, γ-TiCl3. II: δ-TiCl3

2. Syntheses, Structure, and Reactivity of Chiral Titanium Compounds: Procatalysts for Olefin Polymerization

3. Steric Effects in Reactions of Decamethyltitanocene Hydride with Internal Alkynes, Conjugated Diynes, and Conjugated Dienes

4. Radical-Based Epoxide Opening by Titanocenes

5. Probing the Coordinative Unsaturation and Local Environment of Ti3+ Sites in an Activated High-Yield Ziegler-Natta Catalyst

Cited by 8 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Controllable synthesis of 2D TiH2 nanoflakes with superior catalytic activity for low-temperature hydrogen cycling of NaAlH4;Chemical Engineering Journal;2022-01

2. Photoinduced Paramagnetic Centers in Nanocomposites Formed by Titanium Dioxide and Myristic Acid;The Journal of Physical Chemistry C;2021-03-23

3. Enhanced Fe-Centered Redox Flexibility in Fe–Ti Heterobimetallic Complexes;Inorganic Chemistry;2019-04-08

4. CpTiCl2 , an Improved Titanocene(III) Catalyst in Organic Synthesis;European Journal of Organic Chemistry;2018-11-09

5. Principles and applications of EPR spectroscopy in the chemical sciences;Chemical Society Reviews;2018