Pb⋯X (X = N, S, I) tetrel bonding interactions in Pb(ii) complexes: X-ray characterization, Hirshfeld surfaces and DFT calculations

Author:

Mahmoudi Ghodrat12345ORCID,Seth Saikat Kumar678910ORCID,Bauzá Antonio10111213ORCID,Zubkov Fedor I.142151617ORCID,Gurbanov Atash V.1819202122ORCID,White Jonathan23242526ORCID,Stilinović Vladimir12272829,Doert Thomas30313233ORCID,Frontera Antonio10111213ORCID

Affiliation:

1. Department of Chemistry

2. Faculty of Science

3. University of Maragheh

4. Maragheh

5. Iran

6. Department of Physics

7. Jadavpur University

8. Kolkata 700032

9. India

10. Departament de Química

11. Universitat de les Illes Balears

12. 07122 Palma (Baleares)

13. Spain

14. Organic Chemistry Department

15. Peoples' Friendship University of Russia (RUDN University)

16. Moscow

17. Russian Federation

18. Department of Organic Chemistry

19. Baku State University

20. Baku

21. Azerbaijan

22. Centro de Química Estrutural

23. BIO-21 Molecular Science and Biotechnology

24. University of Melbourne

25. Parkville

26. Australia

27. University of Zagreb

28. 10000 Zagreb

29. Croatia

30. Department of Chemistry and Food Chemistry

31. Dresden University of Technology

32. 01069 Dresden

33. Germany

Abstract

We report the synthesis and X-ray characterization of four new Pb(ii) complexes of nicotinoylhydrazone and picolinoylhydrazone-based ligands and three different anionic co-ligands (acetate, thiocyanate and iodide) exhibiting relevant tetrel bonding interactions.

Funder

Science and Engineering Research Board

Secretaría de Estado de Investigación, Desarrollo e Innovación

University of Maragheh

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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