Photoinduced molecular transformations. Part 106. Intramolecular addition vsβ-scission of oxyl radicals generated from A-homo-5α-cholest-1-en-4α- and -4β-ol hypoiodites and 4-methyl-A-homo-5α-cholest-1-en-4α- and -4β-ol hypoiodites-Reference-Cited by-同舟云学术

Photoinduced molecular transformations. Part 106. Intramolecular addition vsβ-scission of oxyl radicals generated from A-homo-5α-cholest-1-en-4α- and -4β-ol hypoiodites and 4-methyl-A-homo-5α-cholest-1-en-4α- and -4β-ol hypoiodites

Published:1990 Issue:4 Volume: Page:1033-1039
ISSN:0300-922X
Container-title:J. Chem. Soc., Perkin Trans. 1
language:en
Short-container-title:J. Chem. Soc., Perkin Trans. 1

Author:

Suginome Hiroshi,Yamamoto Yoshimasa,Orito Kazuhiko

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/1990/P1/P19900001033

Reference37 articles.

1. Photoinduced molecular transformations. 104. Pathways of the photorearrangements of five-membered cyclic steroidal .alpha.-nitro ketones to N-hydroxy cyclic imides, cyclic hydroxamic acid, and cyclic imide

2. Photo-induced transformations. Part 57. The formation of bridged oxabicyclic compounds by intramolecular radical addition of oxyl radicals generated from some A-homo-4a-cholesten-3-ol hypoiodites

3. Photo-induced transformations. Part 69. The formation of bridged oxabicyclic compounds by intramolecular radical addition of oxyl radicals generated fromB-homocholest-5-en-7a-ol hypoiodites

4. SYNTHESIS OF 7-OXABICYCLO[2.2.1]HEPTANES FROM 3-CYCLOHEXENOLS INVOLVING PHOTO-INDUCED HYPOIODITE REACTION

5. For reviews on β-scission of alkoxyl radicals see J. M.Surzur, ‘Reactive Intermediates’, ed. R. A. Abramovitch, Plenum, New York, 1982, vol. 2, p. 121;

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1. Reaction and Synthetic Application of Oxygen- Centered Radicals Photochemically Generated from Alkyl Hypohalites;CRC Handbookof Organic Photochemistry and Photobiology, Volumes 1 & 2, Second Edition;2003-09-29

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4. Photoinduced molecular transformations. Part 143. (2 + 2) Photoaddition of 3-hydroxy-1-benzopyran-2-one, 3-benzyloxycarbonyloxy-1-benzopyran-2-one, and their 8-methoxy derivatives, with alkenes and formation of 1,2-disubstituted 1,2-dihydrofuro[2,3-c][1]benzopyran-4-ones by way of β-scission of cyclobutanoxyl radicals generated from the resulting [2 + 2] photoadducts;J. Chem. Soc., Perkin Trans. 1;1993

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