N-Heterocyclic imine-based bis-gallium(<scp>i</scp>) carbene analogs featuring a four-membered Ga<sub>2</sub>N<sub>2</sub> ring-Reference-Cited by-同舟云学术

N-Heterocyclic imine-based bis-gallium(i) carbene analogs featuring a four-membered Ga₂N₂ ring

Published:2023 Issue:35 Volume:52 Page:12454-12460
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wang Bing¹,Chen Wenhao¹,Yang Jiangnan¹,Lu Linfang¹^ORCID,Liu Jiyong²,Shen Liang¹,Wu Di¹³^ORCID

Affiliation:

1. College of Materials, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Hangzhou Normal University, Hangzhou 311121, China

2. Department of Chemistry, Zhejiang University, Hangzhou 310028, China

3. Hubei Key Laboratory of Quality Control of Characteristic Fruits and Vegetables, Hubei Engineering University, Hubei 432000, China

Abstract

A mixture of LDipNLi, tBuOK, and Cp*Ga gave rise to a dinuclear Ga(i) complex. X-ray structure analysis revealed its dimeric structure with a four-membered Ga2N2 ring and DFT studies indicated nonbonding lone pairs at each gallium centre.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Zhejiang Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00782K

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