Controlling selectivity in the reductive activation of CO2 by mixed sandwich uranium(iii) complexes
Author:
Affiliation:
1. Department of Chemsitry
2. School of Life Sciences
3. University of Sussex
4. Brighton BN1 9QJ, UK
5. LPCNO
6. Université de Toulouse
7. INSA Toulouse
8. 31077 Toulouse, France
Abstract
The uranium complexes [U(η8-C8H6(1,4-SiMe3)2)(η5-CpMe4R)] can be tuned to selectively reduce CO2, giving U(iv) complexes incorporating bridging oxo, carbonate, or oxalate groups.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/SC/C4SC01401D
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