Theoretical insights into single-pole quadruple-throw (SP4T) inorganic nonlinear optics molecular switch of Na(HCN)<sub>3</sub>Na: from superalkali to superalkalides-Reference-Cited by-同舟云学术

Theoretical insights into single-pole quadruple-throw (SP4T) inorganic nonlinear optics molecular switch of Na(HCN)₃Na: from superalkali to superalkalides

Published:2022 Issue:44 Volume:10 Page:16789-16802
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Wang Zhi-Jun¹^ORCID,Wang Yin-Feng¹^ORCID,Zeng Jia-Mei¹,Zhang Wen¹,Liu Xue-Xia¹,Li Jia¹,Li Zhi-Ru²^ORCID

Affiliation:

1. Jiangxi Province Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Jinggangshan University, Ji’an, Jiangxi 343009, P. R. China

2. Institute of Theoretical Chemistry, Jilin University, Changchun 130023, P. R. China

Abstract

An electric field can drive electride-like superalkali Na(HCN)3Na (1) switches into superalkalides Na+(HCN)3Na− (2 and 3) via other superalkalides Na+(HCN)3Na− (2a and 3a) to form a SP4T NLO switch.

Funder

National Natural Science Foundation of China

Education Department of Jiangxi Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/TC/D2TC03375E

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