Regulation of microstructure and charge transport properties of cyclopentadiene-based conjugated polymers via side-chain engineering

Author:

Ma Jianeng1,He Qiao2ORCID,Xue Zhongyuan3,Sou Hou Lon2,Han Yang4,Zhong Hongliang3ORCID,Pietrangelo Agostino5,Heeney Martin2ORCID,Fei Zhuping1ORCID

Affiliation:

1. Institute of Molecular Plus, Key Laboratory of Organic Integrated Circuits, Ministry of Education &Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, Tianjin University, Tianjin 300072, China

2. Department of Chemistry and Centre for Processable Electronics, Imperial College London, W12 0BZ, UK

3. School of Chemistry and Chemical Engineering, Shanghai Key Lab of Electrical Insulation and Thermal Aging, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

4. School of Materials Science and Engineering and Tianjin Key Laboratory of Molecular Optoelectronic Science, Tianjin University, Tianjin 300350, China

5. ExxonMobil Technology and Engineering Company, Annandale, New Jersey 08801, USA

Abstract

A series of copolymers of cyclopentadiene and DPP unit with different side chains were synthesized. The copolymer with longer linear alkyl spacer and shorter branches exhibited superior performance and the highest mobility up to 2.1 cm2 V−1 s−1.

Funder

National Natural Science Foundation of China

Seed Foundation of Tianjin University

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

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