Rh(<scp>iii</scp>)-catalyzed substrate-dependent oxidative (spiro)annulation of isoquinolones with diazonaphthoquinones: selective access to new spirocyclic and oxepine-fused polycyclic compounds-Reference-Cited by-同舟云学术

Rh(iii)-catalyzed substrate-dependent oxidative (spiro)annulation of isoquinolones with diazonaphthoquinones: selective access to new spirocyclic and oxepine-fused polycyclic compounds

Published:2022 Issue:23 Volume:9 Page:6598-6605
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Guo Shenghai¹^ORCID,Zhang Ziyi¹,Zhu Yuanqing¹,Wei Zhaotong¹,Zhang Xinying¹^ORCID,Fan Xuesen¹^ORCID

Affiliation:

1. NMPA Key Laboratory for Research and Evaluation of Innovative Drug, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, Henan, China

Abstract

An efficient protocol for the selective synthesis of novel isoquinolone-containing spirocyclic and oxepine-fused polycyclic compounds via rhodium(iii)-catalyzed (spiro)annulation of NH-isoquinolones with diazonaphthalen-2(1H)-ones is reported.

Funder

Science and Technology Department of Henan Province

National Natural Science Foundation of China

Henan Key Laboratory of Organic Functional Molecules and Drug Innovation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D2QO01322C

Reference46 articles.

1. Transition Metal‐Catalyzed Intermolecular Cascade C−H Activation/Annulation Processes for the Synthesis of Polycycles