Flexible NHC-aryloxido aluminum complex and its zwitterionic imidazolium aluminate precursor in ring-opening polymerization of ε-caprolactone-Reference-Cited by-同舟云学术

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Flexible NHC-aryloxido aluminum complex and its zwitterionic imidazolium aluminate precursor in ring-opening polymerization of ε-caprolactone

Published:2024 Issue:3 Volume:53 Page:1346-1354
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Goswami Santu¹,Mandal Pranay¹,Sarkar Subham¹²,Mukherjee Mainak³,Pal Samanwita³^ORCID,Mallick Dibyendu²,Mukherjee Debabrata¹^ORCID

Affiliation:

1. Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur, 741246, West Bengal, India

2. Department of Chemistry, Presidency University, 86/1 College Street, Kolkata, 700073, West Bengal, India

3. Department of Chemistry, Indian Institute of Technology Jodhpur, Karwar, Rajasthan 342037, India

Abstract

An NHC-aryloxide hybrid ligand-bound aluminum complex and its zwitterionic imidazolium precursor catalyze the ring-opening polymerization of ε-caprolactone through two different mechanistic pathways with and without benzyl alcohol as a cocatalyst.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT02932H

Reference104 articles.

1. A stable crystalline carbene

2. An overview of N-heterocyclic carbenes

3. Synthesis and Reactivity of Organosamarium Diarylpnictide Complexes: Cleavage Reactions of Group 15 E−E and E−C Bonds by Samarium(II)

4. Design Concepts for N-Heterocyclic Carbene Ligands

5. Recent advances in the chemistry and applications of N-heterocyclic carbenes

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