Symmetry breaking structural phase transitions, dielectric properties and molecular motions of formamidinium cations in 1D and 2D hybrid compounds: (NH2CHNH2)3[Bi2Cl9] and (NH2CHNH2)3[Bi2Br9]
Author:
Affiliation:
1. Faculty of Chemistry
2. University of Wrocław
3. 50-383 Wrocław
4. Poland
5. Institute of Molecular Physics
6. Polish Academy of Sciences
7. 60-179 Poznań
Abstract
Two organic–inorganic hybrid halobismuthates(iii), (NH2CHNH2)3[Bi2Cl9] (FBC) and (NH2CHNH2)3[Bi2Br9] (FBB), have been prepared with their structures revealed by single-crystal X-ray diffraction at various temperatures.
Funder
Uniwersytet Wrocławski
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02916H
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4. Novel organic–inorganic hybrid ferroelectric: bis(imidazolium) pentachloroantimonate(iii), (C3N2H5)2SbCl5
5. Hybrid salts of binuclear Bi(III) halide complexes with 1,2-bis(pyridinium)ethane cation: Synthesis, structure and luminescent behavior
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