Symmetry breaking structural phase transitions, dielectric properties and molecular motions of formamidinium cations in 1D and 2D hybrid compounds: (NH2CHNH2)3[Bi2Cl9] and (NH2CHNH2)3[Bi2Br9]

Author:

Mencel K.1234,Starynowicz P.1234ORCID,Siczek M.1234ORCID,Piecha-Bisiorek A.1234ORCID,Jakubas R.1234ORCID,Medycki W.5674

Affiliation:

1. Faculty of Chemistry

2. University of Wrocław

3. 50-383 Wrocław

4. Poland

5. Institute of Molecular Physics

6. Polish Academy of Sciences

7. 60-179 Poznań

Abstract

Two organic–inorganic hybrid halobismuthates(iii), (NH2CHNH2)3[Bi2Cl9] (FBC) and (NH2CHNH2)3[Bi2Br9] (FBB), have been prepared with their structures revealed by single-crystal X-ray diffraction at various temperatures.

Funder

Uniwersytet Wrocławski

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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