Exploring the solid state and solution structural chemistry of the utility amide potassium hexamethyldisilazide (KHMDS)-Reference-Cited by-同舟云学术

Exploring the solid state and solution structural chemistry of the utility amide potassium hexamethyldisilazide (KHMDS)

Published:2017 Issue:19 Volume:46 Page:6392-6403
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ojeda-Amador Ana I.¹²³⁴⁵,Martínez-Martínez Antonio J.¹²³⁴⁵,Robertson Gemma M.¹²³⁴⁵,Robertson Stuart D.¹²³⁴⁵,Kennedy Alan R.¹²³⁴⁵^ORCID,O'Hara Charles T.¹²³⁴⁵^ORCID

Affiliation:

1. WestCHEM

2. Department of Pure and Applied Chemistry

3. University of Strathclyde

4. Glasgow

5. UK

Abstract

The coordination chemistry of the important potassium amide KHMDS has been explored both in the solid state and in solution.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01118K

Reference88 articles.

1. Synthetically Important Alkali-Metal Utility Amides: Lithium, Sodium, and Potassium Hexamethyldisilazides, Diisopropylamides, and Tetramethylpiperidides

2. The role of the bis-trimethylsilylamido ligand, [N{SiMe3}2]−, in main group chemistry. Part 1: Structural chemistry of the s-block elements

3. Ion Pair pKs of Some Amines: Extension of the Computed Lithium pK Scale

4. Structural Studies of Cesium, Lithium/Cesium, and Sodium/Cesium Bis(trimethylsilyl)amide (HMDS) Complexes

5. D. C. Bradley , R. G.Copperthwaite, M. W.Extine, W. W.Reichert and M. H.Chisholm, in Inorganic Syntheses, John Wiley & Sons, Inc., 1978, p. 112

Cited by 19 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Potassium Hexamethyldisilazide (KHMDS): Solvent-Dependent Solution Structures;Journal of the American Chemical Society;2024-06-20

2. Enhancing the Metalating Power of ZnEt₂ via Formation of an Alkyl/Alkoxide Potassium Zincate;Helvetica Chimica Acta;2024-02-21

3. Expanding the Coordination of f-Block Metals with Tris[2-(2-methoxyethoxy)ethyl]amine: From Molecular Complexes to Cage-like Structures;Inorganic Chemistry;2023-11-28

4. In Situ Generation of Magnesium‐ and Calcium‐Based Grignard Reagents for Amide Synthesis;Chemistry – A European Journal;2023-06-16

5. Enhancing Metalating Efficiency of the Sodium Amide NaTMP in Arene Borylation Applications;Angewandte Chemie International Edition;2022-05-05