C–H bond activations by the HO˙/(Salophent-Bu)Co(<scp>ii</scp>) radical pair generated via homolysis of a terminal Co(<scp>iii</scp>)

C–H bond activations by the HO˙/(Salophen^t-Bu)Co(ii) radical pair generated via homolysis of a terminal Co(iii)–OH bond

Published:2023 Issue:22 Volume:59 Page:3245-3248
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zhang Jia¹,Li Songyi¹,Fang Huayi¹^ORCID

Affiliation:

1. School of Materials Science and Engineering, Tianjin Key Lab for Rare Earth Materials and Applications, Nankai University, Tianjin, 300350, China

Abstract

The reactive HO˙/(Salophent-Bu)Co(ii) radical pair was generated via a terminal Co(iii)–OH bond homolysis in hydroxocobalt(iii) complexes. Based on this process, C–H bond activations in different substrates were achieved under ambient conditions.

Funder

National Natural Science Foundation of China

Ministry of Science and Technology of the People's Republic of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC00146F

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