Lower critical solution temperature (LCST) phase behaviour of an ionic liquid and its control by supramolecular host–guest interactions

Author:

Dong Shengyi1234,Heyda Jan5678,Yuan Jiayin9104,Schalley Christoph A.1234

Affiliation:

1. Institut für Chemie und Biochemie

2. Freie Universität Berlin

3. 14195 Berlin

4. Germany

5. Physical Chemistry Department

6. University of Chemistry and Technology

7. 16628 Prague 6

8. Czech Republic

9. Max Planck Institute of Colloids and Interfaces

10. 14476 Potsdam

Abstract

Unique LCST phase behaviour of imidazolium-based ionic liquids is reported, which can be controlled by concentration, the choice of cation, anion and solvent, and by supramolecular complex formation. MD simulations provide insight into the molecular basis of this LCST phenomenon.

Funder

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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