Contiguous multiple π-coordination of π-conjugated polyenes: bonding nature and charge delocalization behaviour of polyene–(palladium chain) sandwich clusters-Reference-Cited by-同舟云学术

Contiguous multiple π-coordination of π-conjugated polyenes: bonding nature and charge delocalization behaviour of polyene–(palladium chain) sandwich clusters

Published:2018 Issue:6 Volume:20 Page:4287-4296
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Yamane Mariko¹²³⁴⁵,Yamashita Mitsuki⁶⁷⁸⁹¹⁰,Yamamoto Koji⁶⁷⁸⁹¹⁰,Murahashi Tetsuro⁶⁷⁸⁹¹⁰^ORCID

Affiliation:

1. Department of Applied Chemistry

2. Graduate School of Engineering

3. Osaka University

4. Suita

5. Osaka

6. Department of Chemical Science and Engineering

7. Tokyo Institute of Technology

8. O-okayama

9. Meguro-ku

10. Tokyo

Abstract

We report the bonding nature and charge delocalization behaviour of a series of polyene–(palladium chain) sandwich clusters through systematic ¹³C NMR analysis and molecular orbital analysis.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CP/C7CP06735F

Reference26 articles.

1. Organometallic Sandwich Chains Made of Conjugated Polyenes and Metal−Metal Chains

2. Photoinduced Face-Inversion of Conjugated Tetraene Ligands on a Pd−Pd−Pd Moiety

3. Sandwich Complexes Containing Bent Palladium Chains