Contiguous multiple π-coordination of π-conjugated polyenes: bonding nature and charge delocalization behaviour of polyene–(palladium chain) sandwich clusters
Author:
Affiliation:
1. Department of Applied Chemistry
2. Graduate School of Engineering
3. Osaka University
4. Suita
5. Osaka
6. Department of Chemical Science and Engineering
7. Tokyo Institute of Technology
8. O-okayama
9. Meguro-ku
10. Tokyo
Abstract
We report the bonding nature and charge delocalization behaviour of a series of polyene–(palladium chain) sandwich clusters through systematic 13C NMR analysis and molecular orbital analysis.
Funder
Ministry of Education, Culture, Sports, Science and Technology
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CP/C7CP06735F
Reference26 articles.
1. Organometallic Sandwich Chains Made of Conjugated Polyenes and Metal−Metal Chains
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3. Sandwich Complexes Containing Bent Palladium Chains
4. Stereoretentive Elimination and Trans-olefination of the Dicationic Dipalladium Moiety [Pd2Ln]2+ Bound on 1,3,5-Trienes
5. A stable zerovalent palladium chain enveloped by a π-electron sheath of conjugated polyene ligands
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