Design and synthesis of chromophores with enhanced electro-optic activities in both bulk and plasmonic–organic hybrid devices

Author:

Xu Huajun1ORCID,Elder Delwin L.12ORCID,Johnson Lewis E.12ORCID,Heni Wolfgang34ORCID,de Coene Yovan5ORCID,De Leo Eva34ORCID,Destraz Marcel34,Meier Norbert3,Vander Ghinst Wouter5ORCID,Hammond Scott R.12ORCID,Clays Koen5ORCID,Leuthold Juerg34ORCID,Dalton Larry R.1ORCID,Robinson Bruce H.1ORCID

Affiliation:

1. Department of Chemistry, University of Washington, Seattle, WA 98195, USA

2. Nonlinear Materials Corporation, Seattle, WA 98109, USA

3. Polariton Technologies AG, 8803 Rüschlikon, Switzerland

4. Institute of Electromagnetic Fields, ETH Zurich, Gloriastrasse 35, Zurich 8092, Switzerland

5. Department of Chemistry, University of Leuven, Celestijnenlaan 200D, 3001 Leuven, Belgium

Abstract

By tuning donor strength, we produce an organic electro-optic chromophore with high hyperpolarizability, low absorption, and excellent electro-optic activity, which is demonstrated in a plasmonic–organic hybrid modulator with near record low VπL.

Funder

National Science Foundation

Directorate for Engineering

Fonds Wetenschappelijk Onderzoek

KU Leuven

Air Force Office of Scientific Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Electrical and Electronic Engineering,Process Chemistry and Technology,Mechanics of Materials,General Materials Science

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