Charge-transfer and impulsive electronic-to-vibrational energy conversion in ferricyanide: ultrafast photoelectron and transient infrared studies
Author:
Affiliation:
1. Laboratory of Ultrafast Spectroscopy
2. ISIC, and Lausanne Centre for Ultrafast Science (LACUS)
3. Ecole Polytechnique Fédérale de Lausanne
4. CH-1015 Lausanne
5. Switzerland
6. University of Zurich
7. Department of Chemistry
8. CH-8057 Zürich
Abstract
The photophysics of ferricyanide in H2O, D2O and ethylene glycol was studied upon excitation of ligand-to-metal charge transfer (LMCT) transitions by combining ultrafast photoelectron spectroscopy (PES) of liquids and transient vibrational spectroscopy.
Funder
Swiss National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP03337K
Reference48 articles.
1. Ultrafast Photophysics of Transition Metal Complexes
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4. Excited State Chemistry of the Ferrocyanide Ion in Aqueous Solution. I. Formation of the Hydrated Electron
5. Excited State Chemistry of the Ferrocyanide Ion in Aqueous Solution. II. Photoaquation
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