Alkyne substituted mononuclear photocatalysts based on [RuCl(bpy)(tpy)]+
Author:
Affiliation:
1. Department of Chemistry
2. University of Durham
3. Durham DH1 3LE
4. UK
5. School of Chemistry and Biochemistry
6. University of Western Australia
7. Crawley
8. Australia
Abstract
The introduction of ‘wire-like’ arylene ethynylene substituent to the prototypical water oxidation catalyst precursor [RuCl(2,2′-bipyridine)(2,2′:6′,2′′-terpyridine)]PF6does not significantly alter the photostability of the compounds, nor the ability of the complexes to oxidise 4-methoxybenzyl alcohol to 4-methoxybenzaldehyde.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01278C
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