Selective synthesis of the missing tiara-like Ni10, Ni5 and Ni6 thiolates by the C–S bond cleavage of bis(thioether) molecules with a DFT study-Reference-Cited by-同舟云学术

Selective synthesis of the missing tiara-like Ni₁₀, Ni₅ and Ni₆ thiolates by the C–S bond cleavage of bis(thioether) molecules with a DFT study

Published:2024 Issue:35 Volume:53 Page:14875-14886
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Debnath Suparno¹^ORCID,Giri Sandip¹^ORCID,Mani Ganesan¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Kharagpur, Kharagpur, 721302 India

Abstract

The contrasting reactions of a series of new bis(thioether) molecules with nickel salts have led to synthetic methods selective for particular toroidal nickel(ii) thiolates by the C–S bond cleavage with X-ray structures and DFT study.

Funder

Indian Institute of Science

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT02047B

Reference51 articles.

1. A New Type of Cyclic Transition Metal Complex, [Ni(SC2H5)2]6

2. Nickel Complexes Containing Sterically Demanding Thiolate Ligands: [Ni8S(SC4H9)9]⊖, a Mixed-Valence Nickel Sulfide Thiolate Cluster, and [Ni4(SC3H7)8], a Homoleptic Nickel Thiolate

3. [Ni5(SEt)10] und [Ni4(SC6H11)8], homoleptische Nickel-Thiolate mit pentagonal-prismatischen und cubanartigen Schwefelgerüsten /[Ni5(SEt)10] and [Ni4(SC6H11)8], Homoleptic Nickel-Thiolates with Pentagonal-Prismatic and Cubane-Like Sulfur Frameworks

4. Synthesis and crystal and molecular structure of cyclo-tetrakis[bis(.mu.-N-methylpiperidine-4-thiolato)nickel(II)]

5. Syntheis and structural characterization of cyclo-pentakis [bis(μ-trimethylsilylthiomethane)nickel(II)], [Ni(SCH2SiMe3)2]5, a pentametallic tiara structure