Trifluoro alkyl side chains in the non-fullerene acceptors to optimize the phase miscibility and vertical distribution of organic solar cells

Author:

Zhang Tian12,Chen Haopeng3,Li Chuanfu2,Lu Kun2ORCID,Zhang Liting2,Shokrieh Ahmad2,Zhang Jianqi2ORCID,Lu Guanghao3ORCID,Lei Shengbin1ORCID,Wei Zhixiang2ORCID

Affiliation:

1. Tianjin Key Laboratory of Molecular Optoelectronic, Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China

2. CAS Key Laboratory of Nano System and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China

3. Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an 710049, China

Abstract

By introducing the trifluoride group to control the compatibility of the material, the acceptor tends to cluster in the upper part of the active layer, which helps to shorten the exciton transport channel and increase the collection of excitons.

Funder

National Natural Science Foundation of China

Youth Innovation Promotion Association of the Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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