Ti-catalyzed ring-opening oxidative amination of methylenecyclopropanes with diazenes-Reference-Cited by-同舟云学术

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Ti-catalyzed ring-opening oxidative amination of methylenecyclopropanes with diazenes

Published:2020 Issue:27 Volume:11 Page:7204-7209
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Beaumier Evan P.¹²³⁴^ORCID,Ott Amy A.¹²³⁴^ORCID,Wen Xuelan¹²³⁴^ORCID,Davis-Gilbert Zachary W.¹²³⁴^ORCID,Wheeler T. Alexander¹²³⁴^ORCID,Topczewski Joseph J.¹²³⁴^ORCID,Goodpaster Jason D.¹²³⁴^ORCID,Tonks Ian A.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Minnesota – Twin Cities

3. Minneapolis MN 55455

4. USA

Abstract

The ring-opening oxidative amination of methylenecyclopropanes (MCPs) with diazenes catalyzed by py₃TiCl₂(NR) complexes is reported.

Funder

National Institutes of Health

Alfred P. Sloan Foundation

Office of Science

National Institute of General Medical Sciences

University of Minnesota

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC01998D

Reference57 articles.

1. Transition Metal-Catalyzed C–H Amination: Scope, Mechanism, and Applications

2. Oxidative C–H amination reactions

3. Directing-Group-Assisted Transition-Metal-Catalyzed Direct Intermolecular C−H Amidation and Amination of Arenes

4. Transition Metal‐Catalyzed Formation of N‐Heterocycles via Aryl‐ or Vinyl C–H Bond Amination

5. Transition-Metal-Catalyzed C–N Bond Forming Reactions Using Organic Azides as the Nitrogen Source: A Journey for the Mild and Versatile C–H Amination

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