Direct conversion of carboxylic acids to free thiols <i>via</i> radical relay acridine photocatalysis enabled by N

Direct conversion of carboxylic acids to free thiols via radical relay acridine photocatalysis enabled by N–O bond cleavage

Published:2024 Issue:2 Volume:15 Page:644-650
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Lipilin Dmitry L.¹,Zubkov Mikhail O.¹^ORCID,Kosobokov Mikhail D.¹^ORCID,Dilman Alexander D.¹^ORCID

Affiliation:

1. N. D. Zelinsky Institute of Organic Chemistry, Leninsky Prosp. 47, 119991 Moscow, Russian Federation

Abstract

A method for the one pot conversion of acids to free thiols is described. The reaction is based on the ability of a novel sulfur reagent to maintain regeneration of the acridine photocatalyst.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC05513B

Reference74 articles.

1. Organocatalytic Carbon–Sulfur Bond-Forming Reactions

2. Transition-Metal-Catalyzed C–S, C–Se, and C–Te Bond Formations via Cross-Coupling and Atom-Economic Addition Reactions. Achievements and Challenges

3. Metal-Catalyzed Carbon−Sulfur Bond Formation

4. Transition-Metal-Catalyzed C−S, C−Se, and C−Te Bond Formation via Cross-Coupling and Atom-Economic Addition Reactions

5. Radical approaches to C–S bonds

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Multimodal Acridine Photocatalysis Enables Direct Access to Thiols from Carboxylic Acids and Elemental Sulfur;ACS Catalysis;2024-04-19

2. Dual Acridine/Decatungstate Photocatalysis for the Decarboxylative Radical Addition of Carboxylic Acids to Azomethines;Organic Letters;2024-04-08

3. Acridine photocatalysis enables tricomponent direct decarboxylative amine construction;Chemical Science;2024