Trifluoromethanesulfonyloxy-group-directed regioselective (3 + 2) cycloadditions of benzynes for the synthesis of functionalized benzo-fused heterocycles-Reference-Cited by-同舟云学术

Trifluoromethanesulfonyloxy-group-directed regioselective (3 + 2) cycloadditions of benzynes for the synthesis of functionalized benzo-fused heterocycles

Published:2015 Issue:2 Volume:13 Page:520-526
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Ikawa Takashi¹²³⁴,Kaneko Hideki¹²³⁴,Masuda Shigeaki¹²³⁴,Ishitsubo Erika⁵⁶⁷⁸⁴,Tokiwa Hiroaki⁵⁶⁷⁸⁴,Akai Shuji¹²³⁴

Affiliation:

1. Graduate School of Pharmaceutical Sciences

2. Osaka University

3. Suita

4. Japan

5. Department of Chemistry

6. Research for Smart Molecules

7. Rikkyo University

8. Toshimaku

Abstract

Highly regioselective (3 + 2) cycloadditions of 3- and 4-TfO-benzynes with 1,3-dipoles followed by cross-coupling reactions provided multisubstituted benzo-fused heterocycles.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C4OB01627K

Reference69 articles.

1. RECENT APPLICATIONS OF ARYNE CHEMISTRY TO ORGANIC SYNTHESIS. A REVIEW

2. Aryne,ortho-Quinone Methide, andortho-Quinodimethane: Synthesis of Multisubstituted Arenes Using the Aromatic Reactive Intermediates

3. A Comprehensive History of Arynes in Natural Product Total Synthesis

4. A Closer Look at Aryne Chemistry: Details that Remain Mysterious

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