Crystal structures, bonding and electronic structures of α- and β-Ir2B3−x compounds-Reference-Cited by-同舟云学术

Crystal structures, bonding and electronic structures of α- and β-Ir₂B_3−x compounds

Published:2024 Issue: Volume: Page:
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sologub Oksana¹^ORCID,Salamakha Leonid P.¹²^ORCID,Stöger Berthold³^ORCID,Mori Takao⁴^ORCID,Barisic Neven¹⁵^ORCID,Rogl Peter F.⁶^ORCID,Michor Herwig¹^ORCID,Bauer Ernst¹^ORCID

Affiliation:

1. Institute of Solid State Physics, TU Wien, A-1040 Vienna, Austria

2. Department of Physics of Metals, Faculty of Physics, I. Franko L'viv National University, 79005, L'viv, Ukraine

3. X-Ray Centre, TU Wien, A-1060 Vienna, Austria

4. National Institute for Materials Science (NIMS), Research Center for Materials Nanoarchitectonics (MANA), Tsukuba, Japan

5. Department of Physics, Faculty of Science, University of Zagreb, Croatia

6. Institute of Materials Chemistry, University of Vienna, A-1090 Vienna, Austria

Abstract

α-Ir2B3−x and β-Ir2B3−x exhibit strong interactions between Ir and B; however, β-Ir2B3−x demonstrates a negligible covalent bonding component in the boron subunits compared to strong covalent bonding in the chair-like boron hexagons of α-Ir2B3−x.

Funder

Austrian Science Fund

Hrvatska Zaklada za Znanost

Japan Science and Technology Agency

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT02095B

Reference68 articles.

1. Rediscovering the Crystal Chemistry of Borides

2. Ultraincompressible, Superhard Materials

3. B.Albert and K.Hofmann , Metal borides: versatile structures and properties , in Handbook of Solid State Chemistry , 2017 , pp. 435–453

4. Boron: Enabling Exciting Metal-Rich Structures and Magnetic Properties

5. Perspective: Superhard metal borides: A look forward